CsPbI₃ asosidagi perovskit quyosh elementlarining samaradorligini tadqiq etish
Study of the efficiency of CsPbI₃-based perovskite solar cells
Article Sidebar
Main Article Content
Abstract
In this work, the photovoltaic parameters of CsPbI₃ perovskite solar cells were investigated by controlling the thermal annealing temperature and the layer thickness. The CsPbI₃ perovskite active layers were prepared from a 0.3 M solution of CsI and PbI₂ (1:1 molar ratio) in MAAc by one-, two-, three- and four-cycle spin coating. The thermal annealing temperature of the CsPbI₃ layer was varied in the range of 90–120 °C, and the layer thickness was controlled by depositing the perovskite active layer several times by spin coating. This approach made it possible to systematically assess the effect of the number of spin-coated perovskite layers and the thermal treatment temperature on the photovoltaic performance of CsPbI₃ perovskite solar cells.
Article Details
Section
This work is licensed under a Creative Commons Attribution 4.0 International License.
How to Cite
References
Kojima, A., Teshima, K., Shirai, Y., Miyasaka, T. Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells. Journal of the American Chemical Society, 2009, 131, 6050–6051. DOI: https://doi.org/10.1021/ja809598r
Green, M.A., Ho-Baillie, A., Snaith, H.J. The emergence of perovskite solar cells. Nature Photonics, 2014, 8, 506–514. DOI: https://doi.org/10.1038/nphoton.2014.134
Eperon, G.E., Stranks, S.D., Menelaou, C., Johnston, M.B., Herz, L.M., Snaith, H.J. Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells. Energy & Environmental Science, 2014, 7, 982–988. DOI: https://doi.org/10.1039/c3ee43822h
Swarnkar, A., Marshall, A.R., Sanehira, E.M., et al. Quantum dot-induced phase stabilization of α-CsPbI₃ perovskite for high-efficiency photovoltaics. Science, 2016, 354, 92–95.
Hu, Y., Bai, F., Liu, X., Ji, Q., Miao, X., Qiu, T., Zhang, S. Bismuth Incorporation Stabilized α-CsPbI₃ for Fully Inorganic Perovskite Solar Cells. ACS Energy Letters, 2017, 2, 2219–2227. DOI: https://doi.org/10.1021/acsenergylett.7b00508
Liang, J., Zhao, P., Wang, C., Wang, Y., Hu, Y., Zhu, G., Ma, L., Liu, J., Jin, Z. CsPb₀.₉Sn₀.₁IBr₂ Based All-Inorganic Perovskite Solar Cells with Exceptional Efficiency and Stability. Journal of the American Chemical Society, 2017, 139, 14009–14012. DOI: https://doi.org/10.1021/jacs.7b07949
Lau, C.F.J., Zhang, M., Deng, X., Zheng, J., Bing, J., Ma, Q., Kim, J., Hu, L., Green, M.A., Huang, S., et al. Strontium-Doped Low-Temperature-Processed CsPbI₂Br Perovskite Solar Cells. ACS Energy Letters, 2017, 2, 2319–2325. DOI: https://doi.org/10.1021/acsenergylett.7b00751
Xiang, W., Wang, Z., Kubicki, D.J., Tress, W., Luo, J., Prochowicz, D., Akin, S., Emsley, L., Zhou, J., Dietler, G., et al. Europium-Doped CsPbI₂Br for Stable and Highly Efficient Inorganic Perovskite Solar Cells. Joule, 2019, 3, 205–214. DOI: https://doi.org/10.1016/j.joule.2018.10.008
Yao, H., Zhao, J., Li, Z., Ci, Z., Jin, Z. Research and progress of black metastable phase CsPbI₃ solar cells. Materials Chemistry Frontiers, 2021, 5, 1221–1235. DOI: https://doi.org/10.1039/D0QM00756K
Liu, D., Shao, Z., Li, C., Pang, S., Yan, Y., Cui, G. Structural Properties and Stability of Inorganic CsPbI₃ Perovskites. Small Structures, 2021, 2, 2000089. DOI: https://doi.org/10.1002/sstr.202000089
Yao, Z., Zhao, W., Liu, S.F. Stability of the CsPbI₃ perovskite: from fundamentals to improvements. Journal of Materials Chemistry A, 2021, 9, 11124–11144. DOI: https://doi.org/10.1039/D1TA01252E
Li, Z., Zhou, F., Wang, Q., Ding, L., Jin, Z. Approaches for thermodynamically stabilized CsPbI₃ solar cells. Nano Energy, 2020, 71, 104634. DOI: https://doi.org/10.1016/j.nanoen.2020.104634
Eperon, Giles E., et al. "Inorganic caesium lead iodide perovskite solar cells." Journal of Materials Chemistry A 3.39 (2015): 19688-19695. DOI: https://doi.org/10.1039/C5TA06398A
Sutton, Rebecca J., et al. "Cubic or orthorhombic? Revealing the crystal structure of metastable black-phase CsPbI3 by theory and experiment." ACS Energy Letters 3.8 (2018): 1787-1794. DOI: https://doi.org/10.1021/acsenergylett.8b00672
Swarnkar, Abhishek, et al. "Quantum dot–induced phase stabilization of α-CsPbI3 perovskite for high-efficiency photovoltaics." Science 354.6308 (2016): 92-95. DOI: https://doi.org/10.1126/science.aag2700